If you want to have some further reading on VB.Net, the following books may be of interest. I would say that the marketplace is greater in C# than VB.Net, however if you come from VB6 then this would be a good natural progression

	This book is for anyone who wants to write good Visual Basic 2008 code, even if you have never programmed before. Writing good code can be a challenge, there are so many options, especially in a language like Visual Basic. If you want to really get the best from a programming language you need to know which features work best in which situations and understand their strengths and weaknesses. It is this understanding that makes the difference between coding and coding well. Beginning VB 2008 has been written to teach you how to use the Visual Basic programming language to solve problems. From the earliest chapters, and from the first introductory concepts, you'll be looking at real-world programming challenges and learning how Visual Basic can be used to overcome them. As you progress through the book the problems become more involved and interesting while the solutions become correspondingly more complex and powerful as Visual Basic features interact to achieve the results that you want.
	Beginning VB 2008 Databases is for every VB programmer. This book assumes no prior database experience, and teaches, always through hands-on examples, how to create and use relational databases with the standard database language SQL and how to access them with VB. Almost every application needs to access a database, and this book concisely teaches all the fundamentals needed—and most that are ever needed—to develop professional database applications.
	The most up-to-date and comprehensive introductory ASP.NET book you’ll find on any shelf, Beginning ASP.NET 4 in VB 2010 guides you through Microsoft’s latest technology for building dynamic web sites. This book will enable you to build dynamic web pages on the fly, and assumes only the most basic knowledge of Visual Basic. The book provides exhaustive coverage of ASP.NET, guiding you from your first steps right up to the most advanced techniques, such as querying databases from within a web page and tuning your site for optimal performance. Within these pages, you’ll find tips for best practices and comprehensive discussions of key database and XML principles you need to know in order to be effective with ASP.NET. The book also emphasizes the invaluable coding techniques of object orientation and code-behind, which will start you off on the track to building real-world web sites right from the beginning—rather than just faking it with simplified coding practices.
	I love Andrews' books, excellent author. Whether you’re moving to .NET for the first time, or you’re already writing applications on .NET 2.0 or .NET 3.0, Pro VB 2008 and the .NET 3.5 Platform will provide you with a solid grounding in this technology and serve as a comprehensive reference throughout your coding career